Monday, March 05, 2007

Determination of Molecular Mass by Dumas’ Method

Determination of Molecular Mass by Dumas’ Method
A gas will behave like an ideal gas under low pressure and high temperature ( p << pc and T >> Tc). As the gas tends to ideality, it is possible to apply the ideal gas law (pV = nRT) to calculate the molecular mass of an unknown gas (Mr = mass x RT/ pV). Where R is the gas constant 8.3143 m3·Pa·K-1·mol-1 and T is temperature in Kelvins

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Warming up of the Dumas Bulb in a hot water bath

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On cooling the bulb, the sample will be sucked into the bulb via the capillary.

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Sealing of the Dumas Bulb after all the unknown liquid sample has been vaporised, with the Dumas Bulb still in the hot water bath.

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Using of water to determine the vol of gas that occupied the Dumas Bulb.

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